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Glass Transition Temperatures

Amorphous Polymer Tg1
(K)
Poly(chlorotrifluoroethylene) 360
Poly(vinyl chloride), PVC 356
Poly(vinyl fluoride), PVF 326
Poly(vinylidene chloride), PVDC 256
Poly(vinylidene fluoride), PVDF 240
Teflon, PTFE 392
Polychloroprene, Neoprene 237
Poly(acrylamide) 438
Poly(N,N-dimethylacrylamide) 379
Poly(2-cyanobutyl acrylate) 384
Poly(2-cyanoethyl acrylate) 277
Poly(2-ethylhexyl acrylate)  221
Poly(2,2,3,3-tetrafluoropropyl acrylate) 249
Poly(3,3,5-trimethylcyclohexyl acrylate) 302
Poly(4-cyanobutyl acrylate) 236
Poly(acrylic acid), PAA 374
Poly(benzyl acrylate) 277
Poly(butyl acrylate)  220
Poly(cyanomethyl acrylate) 296
Poly(cyclohexyl acrylate) 288
Poly(dodecyl acrylate) 255
Poly(ethyl acrylate) 250
Poly(hexyl acrylate)   215
Poly(isobornyl acrylate) 359
Poly(isobutyl acrylate) 240
Poly(isopropyl acrylate) 271
Poly(methyl acrylate), PMA 283
Poly(nonyl acrylate) 200
Poly(octadecyl acrylate)  314
Poly(phenoxyethyl acrylate) 279
Poly(propyl acrylate) 231
Poly(sec-butyl acrylate) 253
Poly(tert-butyl acrylate) 311
Poly(tetrahydro furfuryl acrylate) 260
Poly(1-butene) 244
Poly(1-octene) 218
Poly(1-pentene) 238
Poly(4-methylpent-1-ene) 302
Poly(cyclohexylethene) 393
Poly(ethylene) 193
Poly(isobutene) 203
Poly(propylene) 263
Poly[1-(tert-butyl)ethene] 337
Poly(heptane-1,7-diyl teraphthalamide) 390
Poly(8-aminooctanoic acid), Nylon 8 323
Poly(caprolactam), Nylon 6 324
Poly(hexamethylene adipamide), Nylon 6,6 324
Poly(hexamethylene sebacamide), Nylon 6,10 320
Poly(iminoadipoyliminoheptamethylene), Nylon 7,6 326
Poly(iminosebacoyliminodecamethylene), Nylon 10,10 326
Poly(m-phenylene terephthalamide), Nomex MPDI 537
Poly(p-phenylene terephthalamide), Kevlar, PPTA 600
Poly(ω-dodecanamide), Nylon 12 313
Poly(ω-undecanamide), Nylon 11 317
Poly(4,4'-methylenedioxy dibenzoic anhydride) 407
Poly(4,4'-pentamethylenedibenzoic anhydride) 320
Poly(4,4'-tetramethylenedibenzoic anhydride) 316
Poly(isophthalic anhydride) 385
Poly(1,2-ethylene carbonate)  290
Poly(1,2-propylene carbonate) , PPC 310
Poly(1,4-cyclohexanecarbonate)  400
Poly(1,5-pentylene carbonate) 277
Poly(1,6-hexylene carbonate) 271
Poly(1,8-octylene carbonate) 266
Poly(2,6,3',5'-tetrachloro bisphenol A carbonate) 500
Poly(3,3'-oxydiphenylene carbonate) 364
Poly(4,4'-thiodiphenylene carbonate) 391
Poly(Bisphenol A carbonate) 424
Poly(Bisphenol AP carbonate) 460
Poly(Bisphenol B carbonate) 415
Poly(Bisphenol C carbonate) 381
Poly(tetramethyl Bisphenol A carbonate) 467
Poly(Bisphenol E carbonate) 416
Poly(Bisphenol F carbonate) 407
Poly(methyl cyanoacrylate) 436
Poly(ethyl cyanoacrylate) 422
Poly(butyl cyanoacrylate) 379
PoIy(1,2-butadiene) 261
PoIy(1-pentenylene) 176
Poly(1,4-butadiene) 168
Poly(1-methyl-1-butenylene) 203
Poly(norbornene) 316
Poly(1,4-butylene adipate) 205
Poly(2-ethyl-2-methylpropylene terephthalate) 328
Poly(1,4-butane sebacate) 214
Poly(caprolactone) 207
Poly(decamethylene terephthalate) 283
Poly(nonamethylene terephthalate) 289
Poly(ethylene 2,6-naphthalate)  392
Poly(ethylene adipate) 230
Poly(ethylene phthalate) 297
Poly(ethylene terephthalate) 346
Poly(hexamethylene terephthalate) 291
Poly(neopentyl glycol succinate) 257
Poly-(R)-3-hydroxybutyrate 273
Poly(trimethylene terephthalate) 328
Poly[(tetramethylene isophthalate) 297
Poly[(tetramethylene terephthalate) 313
Poly(Bisphenol A terephthalate) 385
Poly(tetramethyl bisphenol A terephthalate) 492
Poly(tetrachloro Bisphenol A terephthalate) 483
Poly(diisopropyl Bisphenol A terephthalate) 408
Poly(diisobutyl Bisphenol A terephthalate) 373
Poly(Bisphenol C terephthalate) 445
Poly(bisphenol AP isophthalate) 473
Polyglycolide, PGL 312
Polylactic acid, PLA 332
Poly(ether ketone ketone), PEKK 437
Poly(4,4'-dichlorobenzophenone), PEK 428
Poly[(hydroquinone)-alt-(4,4'-dichlorobenzophenone)], PEEK 420
Poly{hydroquinone-alt-[1,4-bis(4-fluorobenzoyl)benzene]}, PEEKK 433
Poly(diethyl fumarate) 284
Poly(dimethyl fumarate) 373
Poly(dipropyl fumarate) 259
Poly(3-hexoxypropylene oxide)  189
Poly(1-chloromethyl)ethylene oxide) 250
Poly(epichlorohydrin) 251
Poly(ethylene glycol), PEG 207
Poly(propylene glycol), PPG 200
Poly(tetrahydrofuran), PTHF, PTMG 187
Poly(trimethylene glycol) 197
Polyacetal, Poly(methylene oxide), POM 207
Poly(dimethyl itaconate), PDMI 373
Poly[di(n-propyl) itaconate] 306
Poly(ethyleneketone), PEK 288
poly[(prop-1-ene)-alt-(carbon monooxide)] 312
Poly(1-(Diethylamino)ethyl methacrylate) 293
Poly(1-(Dimethylamino)ethyl methacrylate) 292
Poly(2-hydroxyethyl methacrylate), PHEMA 350
Poly(2-hydroxypropyl methacrylate) 345
Poly(2-phenylethyl methacrylate) 299
Poly(2,2,2-trifluoroethyl methacrylate) 347
Poly(2,2,3,3-tetrafluoropropyl methacrylate) 344
Poly(4-tert-butylcyclohexyl methacrylate) 403
Poly(benzyl methacrylate) 328
Poly(butyl methacrylate) 293
Poly(cyclohexyl methacrylate) 389
Poly(decyl methacrylate) 211
Poly(dodecyl methacrylate) 218
Poly(ethyl methacrylate), PEMA 338
Poly(glycidyl methacrylate) 334
Poly(hexadecyl methacrylate) 289
Poly(hexyl methacrylate) 268
Poly(isobornyl methacrylate) 383
Poly(isobutyl methacrylate) 330
Poly(isodecyl methacrylate) 232
Poly(isopropyl methacrylate)  356
Poly(methacrylic acid), PMAA 501
Poly(methyl methacrylate), PMMA 378
Poly(neopentyl methacrylate) 299
Poly(octadecyl methacrylate) 311
Poly(octyl methacrylate) 228
Poly(pentyl methacrylate) 276
Poly(phenyl methacrylate) 383
Poly(propyl methacrylate) 316
Poly(tert-butyl methacrylate) 388
Poly(tetradecyl methacrylate) 264
Poly(tetrahydrofurfuryl methacrylate) 327
Poly(acrylonitrile), PAN 383
Poly(methacrylonitrile) 388
Poly(2-chloro-p-xylylene) 356
Poly(p-phenylene), PPP 538
Poly(p-xylene) 343
Poly(1,4-phenyl ether), PPE 361
Poly(2,6-dimethyl-p-phenylene oxide), PPO 487
Poly(2,6-diphenyl-p-phenylene oxide) 497
Poly(2-methoxystyrene) 348
Poly(2-methylstyrene) 409
Poly(3-methylstyrene) 370
Poly(4-ethylstyrene) 326
Poly(4-isopropylstyrene) 360
Poly(4-methoxy-2-methylstyrene) 361
Poly(4-methoxystyrene) 386
Poly(4-methylstyrene) 377
Poly(4-phenylstyrene) 423
Poly(4-tert-butylstyrene) 402
Poly(α-methylstyrene), PaMS 445
Polystyrene, PS 373
Poly(2-chlorostyrene) 395
Poly(4-bromostyrene) 411
Poly(4-chlorostyrene) 398
Poly(4-fluorostyrene) 376
Poly(1,4-biphenyl ether ether sulfone), PPSU 482
Poly(1,4-phenylene ether ether sulfone), PEE 479
Poly(1,4-phenylene ether-sulfone), PES 490
Poly(bisphenol S-alt-terephthalic acid) 519
Poly{[bis(4-chlorophenyl)sulfone]-alt-[bisphenol-A]}, PSU 457
Poly(1,4-phenylene sulfide), PPS 363
Poly(ethylene sulfide) 223
Poly(propylene sulfide), PPS 227
Poly[(ethylene glycol)-alt-(hexamethylene diisocyanate)],PEG 50 - HMDI 301
Poly{(ethylene glycol)-alt-[bis(4-isocyanatophenyl)methane]}, EG 50 - MDI 412
Poly(vinyl alcohol), PVOH, PVA 353
Poly(4-hydroxystyrene), PVAc, PVA 430
Poly(vinyl acetate), PVAc, PVA 307
Poly(vinyl benzoate) 344
Poly(vinyl butyrate), PVB 278
Poly(vinyl formate) 307
Poly(vinyl propionate) 283
Poly(vinyl stearate) 318
Poly(butyl vinyl ether) 219
Poly(ethyl vinyl ether) 232
Poly(hexyl vinyl ether) 198
Poly(isobutyl vinyl  ether) 255
Poly(isopropyl vinyl ether)  270
Poly(methyl vinyl ether) 245
Poly(octyl vinyl ether) 193
Poly(propyl vinyl ether) 224
Poly(trifluoromethoxy 1,1-difluoroethylene) 268
Poly(vinyl butyral) 344
Poly(4-chlorophenyl vinyl ketone) 336
Poly(methyl isopropenyl ketone) 370
Poly(phenyl vinyl ketone) 323
Poly(vinyl ethyl ketone) 213
Poly(vinyl methyl ketone) 301
Poly(butyl vinyl thioether) 253
Poly(ethyl vinyl thioether) 266
Poly(methyl vinyl thioether) 272
Poly(vinyl phenyl sulfide) 386
1The Tgs are the average of one or more experimental values