Glass Transition Temperatures

Amorphous Polymer Tg1
(°C)
Poly(chlorotrifluoroethylene) 87
Poly(vinyl chloride), PVC 83
Poly(vinyl fluoride), PVF 52
Poly(vinylidene chloride), PVDC -17
Poly(vinylidene fluoride), PVDF -34
Teflon, PTFE 119
Polychloroprene, Neoprene -36
Poly(acrylamide) 165
Poly(N,N-dimethylacrylamide) 106
Poly(2-cyanobutyl acrylate) 111
Poly(2-cyanoethyl acrylate) 4
Poly(2-ethylhexyl acrylate)  -53
Poly(2,2,3,3-tetrafluoropropyl acrylate) -24
Poly(3,3,5-trimethylcyclohexyl acrylate) 29
Poly(4-cyanobutyl acrylate) -38
Poly(acrylic acid), PAA 101
Poly(benzyl acrylate) 4
Poly(butyl acrylate)  -53
Poly(cyanomethyl acrylate) 23
Poly(cyclohexyl acrylate) 15
Poly(dodecyl acrylate) -19
Poly(ethyl acrylate) -23
Poly(hexyl acrylate)   -59
Poly(isobornyl acrylate) 86
Poly(isobutyl acrylate) -34
Poly(isopropyl acrylate) -2
Poly(methyl acrylate), PMA 10
Poly(nonyl acrylate) -74
Poly(octadecyl acrylate)  40
Poly(phenoxyethyl acrylate) 6
Poly(propyl acrylate) -42
Poly(sec-butyl acrylate) -21
Poly(tert-butyl acrylate) 38
Poly(tetrahydro furfuryl acrylate) -14
Poly(1-butene) -29
Poly(1-octene) -55
Poly(1-pentene) -35
Poly(4-methylpent-1-ene) 29
Poly(cyclohexylethene) 120
Poly(ethylene) -80
Poly(isobutene) -70
Poly(propylene) -10
Poly[1-(tert-butyl)ethene] 64
Poly(heptane-1,7-diyl teraphthalamide) 116
Poly(8-aminooctanoic acid), Nylon 8 50
Poly(caprolactam), Nylon 6 51
Poly(hexamethylene adipamide), Nylon 6,6 51
Poly(hexamethylene sebacamide), Nylon 6,10 46
Poly(iminoadipoyliminoheptamethylene), Nylon 7,6 52
Poly(iminosebacoyliminodecamethylene), Nylon 10,10 53
Poly(m-phenylene terephthalamide), Nomex MPDI 264
Poly(p-phenylene terephthalamide), Kevlar, PPTA 327
Poly(ω-dodecanamide), Nylon 12 40
Poly(ω-undecanamide), Nylon 11 44
Poly(4,4'-methylenedioxy dibenzoic anhydride) 134
Poly(4,4'-pentamethylenedibenzoic anhydride) 47
Poly(4,4'-tetramethylenedibenzoic anhydride) 43
Poly(isophthalic anhydride) 112
Poly(1,2-ethylene carbonate)  17
Poly(1,2-propylene carbonate) , PPC 37
Poly(1,4-cyclohexanecarbonate)  127
Poly(1,5-pentylene carbonate) 4
Poly(1,6-hexylene carbonate) -2
Poly(1,8-octylene carbonate) -8
Poly(2,6,3',5'-tetrachloro bisphenol A carbonate) 227
Poly(3,3'-oxydiphenylene carbonate) 90
Poly(4,4'-thiodiphenylene carbonate) 118
Poly(Bisphenol A carbonate) 150
Poly(Bisphenol AP carbonate) 187
Poly(Bisphenol B carbonate) 141
Poly(Bisphenol C carbonate) 108
Poly(tetramethyl Bisphenol A carbonate) 193
Poly(Bisphenol E carbonate) 142
Poly(Bisphenol F carbonate) 134
Poly(methyl cyanoacrylate) 162
Poly(ethyl cyanoacrylate) 149
Poly(butyl cyanoacrylate) 106
PoIy(1,2-butadiene) -13
PoIy(1-pentenylene) -98
Poly(1,4-butadiene) -105
Poly(1-methyl-1-butenylene) -70
Poly(norbornene) 43
Poly(1,4-butylene adipate) -68
Poly(2-ethyl-2-methylpropylene terephthalate) 55
Poly(1,4-butane sebacate) -60
Poly(caprolactone) -66
Poly(decamethylene terephthalate) 10
Poly(nonamethylene terephthalate) 16
Poly(ethylene 2,6-naphthalate)  119
Poly(ethylene adipate) -44
Poly(ethylene phthalate) 24
Poly(ethylene terephthalate) 72
Poly(hexamethylene terephthalate) 18
Poly(neopentyl glycol succinate) -17
Poly-(R)-3-hydroxybutyrate 0
Poly(trimethylene terephthalate) 55
Poly[(tetramethylene isophthalate) 24
Poly[(tetramethylene terephthalate) 40
Poly(Bisphenol A terephthalate) 112
Poly(tetramethyl bisphenol A terephthalate) 218
Poly(tetrachloro Bisphenol A terephthalate) 210
Poly(diisopropyl Bisphenol A terephthalate) 135
Poly(diisobutyl Bisphenol A terephthalate) 100
Poly(Bisphenol C terephthalate) 171
Poly(bisphenol AP isophthalate) 200
Polyglycolide, PGL 39
Polylactic acid, PLA 59
Poly(ether ketone ketone), PEKK 164
Poly(4,4'-dichlorobenzophenone), PEK 155
Poly[(hydroquinone)-alt-(4,4'-dichlorobenzophenone)], PEEK 146
Poly{hydroquinone-alt-[1,4-bis(4-fluorobenzoyl)benzene]}, PEEKK 159
Poly(diethyl fumarate) 10
Poly(dimethyl fumarate) 99
Poly(dipropyl fumarate) -14
Poly(3-hexoxypropylene oxide)  -84
Poly(1-chloromethyl)ethylene oxide) -24
Poly(epichlorohydrin) -22
Poly(ethylene glycol), PEG -67
Poly(propylene glycol), PPG -74
Poly(tetrahydrofuran), PTHF, PTMG -86
Poly(trimethylene glycol) -77
Polyacetal, Poly(methylene oxide), POM -66
Poly(dimethyl itaconate), PDMI 99
Poly[di(n-propyl) itaconate] 32
Poly(ethyleneketone), PEK 15
poly[(prop-1-ene)-alt-(carbon monooxide)] 38
Poly(1-(Diethylamino)ethyl methacrylate) 20
Poly(1-(Dimethylamino)ethyl methacrylate) 18
Poly(2-hydroxyethyl methacrylate), PHEMA 77
Poly(2-hydroxypropyl methacrylate) 72
Poly(2-phenylethyl methacrylate) 26
Poly(2,2,2-trifluoroethyl methacrylate) 74
Poly(2,2,3,3-tetrafluoropropyl methacrylate) 71
Poly(4-tert-butylcyclohexyl methacrylate) 130
Poly(benzyl methacrylate) 55
Poly(butyl methacrylate) 20
Poly(cyclohexyl methacrylate) 116
Poly(decyl methacrylate) -63
Poly(dodecyl methacrylate) -55
Poly(ethyl methacrylate), PEMA 65
Poly(glycidyl methacrylate) 61
Poly(hexadecyl methacrylate) 16
Poly(hexyl methacrylate) -5
Poly(isobornyl methacrylate) 110
Poly(isobutyl methacrylate) 57
Poly(isodecyl methacrylate) -41
Poly(isopropyl methacrylate)  83
Poly(methacrylic acid), PMAA 228
Poly(methyl methacrylate), PMMA 105
Poly(neopentyl methacrylate) 26
Poly(octadecyl methacrylate) 38
Poly(octyl methacrylate) -45
Poly(pentyl methacrylate) 2
Poly(phenyl methacrylate) 110
Poly(propyl methacrylate) 42
Poly(tert-butyl methacrylate) 115
Poly(tetradecyl methacrylate) -9
Poly(tetrahydrofurfuryl methacrylate) 53
Poly(acrylonitrile), PAN 109
Poly(methacrylonitrile) 115
Poly(2-chloro-p-xylylene) 83
Poly(p-phenylene), PPP 265
Poly(p-xylene) 70
Poly(1,4-phenyl ether), PPE 87
Poly(2,6-dimethyl-p-phenylene oxide), PPO 214
Poly(2,6-diphenyl-p-phenylene oxide) 224
Poly(2-methoxystyrene) 75
Poly(2-methylstyrene) 136
Poly(3-methylstyrene) 97
Poly(4-ethylstyrene) 52
Poly(4-isopropylstyrene) 87
Poly(4-methoxy-2-methylstyrene) 87
Poly(4-methoxystyrene) 113
Poly(4-methylstyrene) 104
Poly(4-phenylstyrene) 149
Poly(4-tert-butylstyrene) 129
Poly(α-methylstyrene), PaMS 172
Polystyrene, PS 100
Poly(2-chlorostyrene) 122
Poly(4-bromostyrene) 138
Poly(4-chlorostyrene) 125
Poly(4-fluorostyrene) 103
Poly(1,4-biphenyl ether ether sulfone), PPSU 209
Poly(1,4-phenylene ether ether sulfone), PEE 206
Poly(1,4-phenylene ether-sulfone), PES 217
Poly(bisphenol S-alt-terephthalic acid) 246
Poly{[bis(4-chlorophenyl)sulfone]-alt-[bisphenol-A]}, PSU 183
Poly(1,4-phenylene sulfide), PPS 90
Poly(ethylene sulfide) -50
Poly(propylene sulfide), PPS -46
Poly[(1.4-butanediol)-alt-(1,6-hexamethylene diisocyanate)], PTMG - HMDI 22
Poly[(diethylene glycol)-alt-(1,6-hexamethylene diisocyanate)], PEG 100 - HMDI 8
Poly[(ethylene glycol)-alt-(hexamethylene diisocyanate)],PEG 50 - HMDI 27
Poly{(butane-1,4-diol)-alt-[bis(4-isocyanatophenyl)methane]}, Butane-1,4-diol - MDI 89
Poly{(ethylene glycol)-alt-[bis(4-isocyanatophenyl)methane]}, EG 50 - MDI 139
Poly(vinyl alcohol), PVOH, PVA 80
Poly(4-hydroxystyrene), PVAc, PVA 157
Poly(vinyl acetate), PVAc, PVA 33
Poly(vinyl benzoate) 71
Poly(vinyl butyrate), PVB 5
Poly(vinyl formate) 34
Poly(vinyl propionate) 10
Poly(vinyl stearate) 45
Poly(butyl vinyl ether) -54
Poly(ethyl vinyl ether) -41
Poly(hexyl vinyl ether) -76
Poly(isobutyl vinyl  ether) -19
Poly(isopropyl vinyl ether)  -3
Poly(methyl vinyl ether) -28
Poly(octyl vinyl ether) -80
Poly(propyl vinyl ether) -49
Poly(trifluoromethoxy 1,1-difluoroethylene) -5
Poly(vinyl butyral) 70
Poly(4-chlorophenyl vinyl ketone) 63
Poly(methyl isopropenyl ketone) 97
Poly(phenyl vinyl ketone) 49
Poly(vinyl ethyl ketone) -60
Poly(vinyl methyl ketone) 28
Poly(butyl vinyl thioether) -20
Poly(ethyl vinyl thioether) -7
Poly(methyl vinyl thioether) -1
Poly(vinyl phenyl sulfide) 113
1The Tgs are the average of one or more experimental values.

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